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Chirality-dependent balance between hydrogen bonding and London dispersion in isolated (±)-1-indanol clusters.

dc.contributor.authorAltnöder, Jonas
dc.contributor.authorBouchet, Aude
dc.contributor.authorLee, Juhyon J.
dc.contributor.authorOtto, Katharina E.
dc.contributor.authorSuhm, Martin A.
dc.contributor.authorZehnacker-Rentien, Anne
dc.date.accessioned2014-06-11T12:32:49Z
dc.date.available2014-06-11T12:32:49Z
dc.date.issued2013-07-07
dc.identifier.citationAltnöder, Jonas; Bouchet, Aude; Lee, Juhyon J; Otto, Katharina E; Suhm, Martin A; Zehnacker-Rentien, Anne (2013): Chirality-dependent balance between hydrogen bonding and London dispersion in isolated (±)-1-indanol clusters. - Physical chemistry chemical physics : PCCP, Vol. 15, Nr. 25, p. 10167-80
dc.relation.ISSN1463-9084
dc.identifier.urihttp://resolver.sub.uni-goettingen.de/purl?gs-1/10191
dc.description.abstractThe aggregation behavior of racemic and enantiopure 1-indanol has been studied by FTIR spectroscopy, resonant ion dip IR spectroscopy, and spontaneous Raman scattering in supersonic jets. This triple experimental approach, augmented by homology to related molecular fragments and dispersion-corrected DFT predictions, allows disentangling the complex spectroscopic signature in the OH stretch range. Evidence for chirality-sensitive aggregation via isolated OH···π bonds in competition with cooperative ···OH···OH···π patterns is collected. An accurate description of London dispersion forces provides the key to its explanation.
dc.languageeng
dc.language.isoeng
dc.rightsopenAccess
dc.subjecthydrogen bonding; London dispersion; 1-indanol
dc.titleChirality-dependent balance between hydrogen bonding and London dispersion in isolated (±)-1-indanol clusters.
dc.typejournalArticle
dc.identifier.doi10.1039/c3cp50708d
dc.type.versionpublishedVersion
dc.identifier.fs597481
dc.bibliographicCitation.volume15
dc.bibliographicCitation.issue25
dc.bibliographicCitation.firstPage10167
dc.bibliographicCitation.lastPage10180
dc.type.subtypejournalArticle
dc.identifier.pmid23665542
dc.notesThis publication is with permission of the rights owner freely accessible due to an Alliance licence and a national licence (funded by the DFG, German Research Foundation) respectively.
dc.description.statuspeerReviewed
dc.bibliographicCitation.journalPhysical chemistry chemical physics : PCCP


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