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A Symmetric Recognition Motif between Vicinal Diols: The Fourfold Grip in Ethylene Glycol Dimer.

dc.contributor.authorKollipost, Franz
dc.contributor.authorOtto, Katharina E.
dc.contributor.authorSuhm, Martin A.
dc.date.accessioned2016-07-05T07:55:39Z
dc.date.available2016-07-05T07:55:39Z
dc.date.issued2016-03-24
dc.identifier.citationKollipost, Franz; Otto, Katharina E; Suhm, Martin A (2016): A Symmetric Recognition Motif between Vicinal Diols: The Fourfold Grip in Ethylene Glycol Dimer. - Angewandte Chemie (International ed. in English), Vol. 55, Nr. 14, p. 4591-5
dc.relation.ISSN1521-3773
dc.identifier.urihttp://resolver.sub.uni-goettingen.de/purl?gs-1/13407
dc.description.abstractEthylene glycol has a transiently chiral, asymmetric global minimum structure, but it favors a highly symmetric, achiral dimer arrangement which has not been considered or found in previous quantum-chemical studies. Complementary FTIR and Raman spectroscopy in supersonic jets allows for the detection and straightforward assignment of this four-fold hydrogen-bonded dimer, which introduces an interesting supramolecular binding motif for vicinal diols and provides a strong case for transient chirality synchronization.
dc.languageeng
dc.language.isoeng
dc.rightsopenAccess
dc.rights.urihttps://creativecommons.org/licenses/by-nc/4.0/
dc.subjectdimers; hydrogen bonds; molecular recognition; racemization; vibrational spectroscopy
dc.titleA Symmetric Recognition Motif between Vicinal Diols: The Fourfold Grip in Ethylene Glycol Dimer.
dc.typejournalArticle
dc.identifier.doi10.1002/anie.201600603
dc.type.versionpublishedVersion
dc.bibliographicCitation.volume55
dc.bibliographicCitation.issue14
dc.bibliographicCitation.firstPage4591
dc.bibliographicCitation.lastPage4595
dc.type.subtypejournalArticle
dc.identifier.pmid26929113
dc.description.statuspeerReviewed
dc.bibliographicCitation.journalAngewandte Chemie (International ed. in English)


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