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Iron‐Electrocatalyzed C−H Arylations: Mechanistic Insights into Oxidation‐Induced Reductive Elimination for Ferraelectrocatalysis

dc.contributor.authorZhu, Cuiju
dc.contributor.authorStangier, Maximilian
dc.contributor.authorOliveira, João C. A.
dc.contributor.authorMassignan, Leonardo
dc.contributor.authorAckermann, Lutz
dc.date.accessioned2020-01-14T08:38:58Z
dc.date.available2020-01-14T08:38:58Z
dc.date.issued2019de
dc.relation.ISSN1521-3765de
dc.identifier.urihttp://resolver.sub.uni-goettingen.de/purl?gs-1/17074
dc.description.abstractDespite major advances, organometallic C-H transformations are dominated by precious 5d and 4d transition metals, such as iridium, palladium and rhodium. In contrast, the unique potential of less toxic Earth-abundant 3d metals has been underexplored. While iron is the most naturally abundant transition metal, its use in oxidative, organometallic C-H activation has faced major limitations due to the need for superstoichiometric amounts of corrosive, cost-intensive DCIB as the sacrificial oxidant. To fully address these restrictions, we describe herein the unprecedented merger of electrosynthesis with iron-catalyzed C-H activation through oxidation-induced reductive elimination. Thus, ferra- and manganaelectro-catalyzed C-H arylations were accomplished at mild reaction temperatures with ample scope by the action of sustainable iron catalysts, employing electricity as a benign oxidant.de
dc.language.isoengde
dc.rightsopenAccess
dc.rights.urihttps://creativecommons.org/licenses/by/4.0/
dc.subjectC−H activation; arylation; electricity; electrocatalysis; iron; sustainabilityde
dc.subject.ddc540
dc.titleIron‐Electrocatalyzed C−H Arylations: Mechanistic Insights into Oxidation‐Induced Reductive Elimination for Ferraelectrocatalysisde
dc.typejournalArticlede
dc.identifier.doi10.1002/chem.201904018
dc.type.versionpublishedVersionde
dc.relation.pISSN0947-6539
dc.relation.eISSN1521-3765
dc.bibliographicCitation.volume25de
dc.bibliographicCitation.issue71de
dc.bibliographicCitation.firstPage16382de
dc.bibliographicCitation.lastPage16389de
dc.type.subtypejournalArticle
dc.identifier.pmid31658385
dc.description.statuspeerReviewedde
dc.bibliographicCitation.journalChemistry – A European Journalde


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