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An Unprecedented Fully H - Substituted Phosphate Hydride Sr5(PO4)3H Expanding the Apatite Family

dc.contributor.authorMutschke, Alexander
dc.contributor.authorWylezich, Thomas
dc.contributor.authorRitter, Clemens
dc.contributor.authorKarttunen, Antti J.
dc.contributor.authorKunkel, Nathalie
dc.date.accessioned2020-01-15T10:55:17Z
dc.date.available2020-01-15T10:55:17Z
dc.date.issued2019de
dc.relation.ISSN1434-1948de
dc.identifier.urihttp://resolver.sub.uni-goettingen.de/purl?gs-1/17120
dc.description.abstractThe apatite family is a mineral class that also contains the biologically very important hydroxyapatite. Here, we are reporting on the synthesis and characterization of a fully hydride‐substituted strontium apatite, which could be obtained via mechanochemical synthesis and subsequent annealing treatment. The full substitution by hydride anions is proven by various methods, such as neutron powder diffraction of a deuterated sample Sr5(PO4)3D, as well 1H MAS solid state NMR combined with quantum chemical calculations, vibrational spectroscopy and elemental analysis. The present work expands the apatite family from the known halide and hydroxide apatites to the fully hydride‐anion‐substituted variant and is expected to open up a new field of materials containing coexistent phosphate and hydride anions.de
dc.language.isoengde
dc.rightsopenAccess
dc.rights.urihttps://creativecommons.org/licenses/by-nc-nd/4.0/
dc.subjectMixed anionic compounds; Strontium; Hydrides; Apatites; Mechanochemical synthesis; Neutron diffractionde
dc.subject.ddc540
dc.titleAn Unprecedented Fully H - Substituted Phosphate Hydride Sr5(PO4)3H Expanding the Apatite Familyde
dc.typejournalArticlede
dc.identifier.doi10.1002/ejic.201901151
dc.type.versionpublishedVersionde
dc.bibliographicCitation.volume2019de
dc.bibliographicCitation.issue48de
dc.bibliographicCitation.firstPage5073de
dc.bibliographicCitation.lastPage5076de
dc.type.subtypejournalArticle
dc.description.statuspeerReviewedde
dc.bibliographicCitation.journalEuropean Journal of Inorganic Chemistryde
dc.title.subtitleAn Unprecedented Fully H - -Substituted Phosphate Hydride Sr 5 (PO 4 ) 3 H Expanding the Apatite Family


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